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1 article(s) from Metin, Önder

Exfoliated black phosphorous-mediated CuAAC chemistry for organic and macromolecular synthesis under white LED and near-IR irradiation

Azra Kocaarslan,
Zafer Eroglu,
Önder Metin and
Yusuf Yagci

Beilstein J. Org. Chem. 2021, 17, 2477–2487, doi:10.3762/bjoc.17.164

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Graphical Abstract

Figure 1: Structures of azide and alkyne functional molecules and polymers used in the photoinduced CuAAC rea...

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Figure 2: UV–vis spectra of Cu^ICl, Cu^IICl₂ and BPNs.

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Figure 3: a) ¹H NMR spectra of the model reaction between benzyl azide (Az-1) and phenylacetylene (Alk-3) bef...

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Scheme 1: Proposed mechanism for photoinduced CuAAC reaction using exfoliated BPNs.

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Figure 4: a) ¹H NMR spectrum of chain end modified PCL-Anth; b) UV–vis spectra of (azidomethyl)anthracene (bl...

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Scheme 2: Synthesis of PS-b-PCL block copolymer via exfoliated BPNs-mediated photoinduced CuAAC reaction.

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Figure 5: a) GPC traces of PS-Az, PCL-Alk and block copolymer (Ps-b-PCL) b) ¹H NMR spectrum of the block copo...

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Scheme 3: Preparation of the cross-linked polymer by CuAAC reaction using multifunctional monomers, Az-3 and ...

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Figure 6: a) DSC thermogram of photoinduced synthesis of nanocomposite networks (heating rate: 10 °C/min). b)...

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Figure 7: (a, b) TEM images of cross-linked polymer at two different magnifications, c) HAADF-STEM image and ...

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Published 23 Sep 2021

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